Behavior of Mild Steels by the Action of Corrosion Inhibitors Alone or in Combination in a NaCl Environment
Keywords:
Corrosion, Steel, Inhibitor, K2MoO4, ZnCl2
Abstract
Steel prevention from corrosion is considered one of the essential topics in the industries, of the fatal consequences of this phenomenon. The intention of the research is to look at zinc chloride and potassium molybdate efficiency as mild steel corrosion inhibitors in a harsh environment (NaCl).
The results achieved using standard stationary I=f(E) and non-stationary electrochemical techniques (electrochemical impedance) and the mass loss methodology allowed us to evaluate the mixing role of the two inhibitors for better steel protection.
References
1. Ferkous, H., Djellali, S., Sahraoui, R., Benguerba, Y., Behloul, H., Çukurovali, A.: Corrosion inhibition of mild steel by 2-(2-methoxybenzylidene) hydrazine-1-carbothioamide in hydrochloric acid solution: Experimental measurements and quantum chemical calculations. J. Mol. Liq. 307, 112957 (2020).
2. Prajila, M., Ammal, P.R., Joseph, A.: Comparative studies on the corrosion inhibition characteristics of three different triazine based Schiff’s bases, HMMT, DHMMT and MHMMT, for mild steel exposed in sulfuric acid. Egypt. J. Pet. 27, 467–475 (2018). https://doi.org/10.1016/j.ejpe.2017.07.011.
3. Kamali Ardakani, E., Kowsari, E., Ehsani, A.: Imidazolium-derived polymeric ionic liquid as a green inhibitor for corrosion inhibition of mild steel in 1.0 M HCl: Experimental and computational study. Colloids Surf. Physicochem. Eng. Asp. 586, 124195 (2020). https://doi.org/10.1016/j.colsurfa.2019.124195.
4. Rizi, A., Sedik, A., Acidi, A., Rachedi, K.O., Ferkous, H., Berredjem, M., Delimi, A., Abdennouri, A., ALAM, M., Ernst, B., Benguerba, Y.: Sustainable and Green Corrosion Inhibition of Mild Steel: Insights from Electrochemical and Computational Approaches. ACS Omega. 8, 47224–47238 (2023). https://doi.org/10.1021/acsomega.3c06548.
5. Ferkous, H., Sedik, A., Delimi, A., Redjemia, R., Abdesalem, K., Boulechfar, C., Abdennouri, A., Madaci, A., Berredjem, M., Boublia, A., Sajid Ali, M., Jeon, B.-H., Kumar Yadav, K., Benguerba, Y.: A comparative study of novel synthesized sulfamide compounds: Electrochemical, morphological, XPS, and theoretical investigations on copper corrosion inhibition in 1.0 M HCl. J. Mol. Liq. 394, 123781 (2024). https://doi.org/10.1016/j.molliq.2023.123781.
6. Koch, G., Varney, J., Thompson, N., Moghissi, O., Gould, M., Payer, J.: International measures of prevention, application, and economics of corrosion technologies study. NACE Int. 216, 2–3 (2016).
7. Thapa Magar, J., Budhathoki, I.K., Rajaure, A., Oli, H.B., Bhattarai, D.P.: Alkaloid Extract of Ageratina adenophora Stem as Green Inhibitor for Mild Steel Corrosion in One Molar Sulfuric Acid Solution. Electrochem. 4, 84–102 (2023). https://doi.org/10.3390/electrochem4010009.
8. Ferkous, H., Delimi, A., Abdesalem, K., BOULECHFAR, C., Djellali, S., Belakhdar, A., Yadav, K.K., Ali, I., Ahmad, A., Ahn, H.-J., Abdellattif, M., Jeon, B.-H., Benguerba, Y.: Electrochemical and Computational Approaches of Polymer Coating on Carbon Steel X52 in Different Soil Extracts. Polymers. 14, (2022). https://doi.org/10.3390/polym14163288.
9. Lahbib, H., Ben Hassen, S., Gerengi, H., Ben Amor, Y.: Inhibition effect of Cynara cardunculus leaf extract on corrosion of St37 steel immersed in seawater with and without bleach solution. Chem. Eng. Commun. 208, 1260–1278 (2021). https://doi.org/10.1080/00986445.2020.1771320.
10. Ould Sidine, M., Lahbib, H., Hadou, A., Ba, M., Benmessaoud, M., ben amor, Y., Elemine, B.: Usage of Grewia bicolor Juss leaves extract as green corrosion inhibitor for Steel XC40 in sulfuric acid medium. Int. J. Corros. Scale Inhib. 12, 961–983 (2023). https://doi.org/10.17675/2305-6894-2023-12-3-10.
11. Gabsi, M., Ferkous, H., Delimi, A., Boublia, A., Boulechfar, C., Kahlouche, A., Darwish, A.S., Lemaoui, T., Benguerba, Y.: The curious case of polyphenols as green corrosion inhibitors: a review on their extraction, design, and applications. Environ. Sci. Pollut. Res. 30, 59081–59105 (2023). https://doi.org/10.1007/s11356-023-26753-4.
12. Boukerche, S., Ferkous, H., Delimi, A., Sedik, A., Djedouani, A., Otmane Rachedi, K., Bouchoukh, H., Berredjem, M., Zahzouh, M., Himour, A., Bellucci, S., Alam, M., Benguerba, Y.: Anti-corrosion performance of dehydroacetic acid thiosemicarbazone on XC38 carbon steel in an acidic medium. Arab. J. Chem. 16, 105061 (2023). https://doi.org/10.1016/j.arabjc.2023.105061.
13. Madaci, A., Ferkous, H., Sedik, A., Delimi, A., Boulechfar, C., Belakhdar, A., Berredjem, M., Chaouch, M.A., Alam, M., Majdoub, H., Jaffrezic-Renault, N., Benguerba, Y.: Experimental and theoretical study of polysaccharides extracted from prickly pear nopales Pulp (PPUN) of Opuntia ficus-indica as corrosion inhibitors. J. Mol. Liq. 384, 122272 (2023). https://doi.org/10.1016/j.molliq.2023.122272.
14. Belakhdar, A., Ferkous, H., Djellali, S., Sahraoui, R., Lahbib, H., Amor, Y.B., Erto, A., Balsamo, M., Benguerba, Y.: Computational and experimental studies on the efficiency of Rosmarinus officinalis polyphenols as green corrosion inhibitors for XC48 steel in acidic medium. Colloids Surf. Physicochem. Eng. Asp. 606, 125458 (2020).
15. Haldhar, R., Prasad, D., Bhardwaj, N.: Extraction and experimental studies of Citrus aurantifolia as an economical and green corrosion inhibitor for mild steel in acidic media. J. Adhes. Sci. Technol. 33, 1169–1183 (2019). https://doi.org/10.1080/01694243.2019.1585030.
16. Sun, Y., Zhang, Y., Xu, C., Tan, B., Li, W., Zheng, X., Brahmia, A.: Honeysuckle extract as an environment-friendly corrosion inhibitor for copper in sulfuric acid medium. Ind. Crops Prod. 197, 116551 (2023). https://doi.org/10.1016/j.indcrop.2023.116551.
17. Djellali, S., Ferkous, H., Sahraoui, R., Meharga, S.: Efficiency of Alkaloids Crude Extract of Cinnamomum Zeylanicum as Corrosion Inhibitor of Mild Steel in Sulfuric Acid Solution. In: Euro-Mediterranean Conference for Environmental Integration. pp. 1379–1384. Springer (2019).
18. Lahbib, H., Ben Hassen, S., Gerengi, H., Rizvi, M., Ben Amor, Y.: Corrosion inhibition performance of dwarf palm and Cynara cardunculus leaves extract for St37 steel in 15% H2SO4: a comparative study. J. Adhes. Sci. Technol. 35, 691–722 (2021).
19. Belakhdar, A., Ferkous, H., Djellali, S., Sahraoui, R., Lahbib, H., Amor, Y.B.: Corrosion inhibition performance of Rosmarinus officinalis methanolic extract on carbon steel XC48 in acidic medium (2M HCl). Mater. Biomater. Sci. 3, 046–053 (2020).
20. Boulechfar, C., Ferkous, H., Djellali, S., Amin, M.A., Boufas, S., Djedouani, A., Delimi, A., Ben Amor, Y., Kumar Yadav, K., Jeon, B.-H., Benguerba, Y.: DFT/molecular scale, MD simulation and assessment of the eco-friendly anti-corrosion performance of a novel Schiff base on XC38 carbon steel in acidic medium. J. Mol. Liq. 344, 117874 (2021). https://doi.org/10.1016/j.molliq.2021.117874.
2. Prajila, M., Ammal, P.R., Joseph, A.: Comparative studies on the corrosion inhibition characteristics of three different triazine based Schiff’s bases, HMMT, DHMMT and MHMMT, for mild steel exposed in sulfuric acid. Egypt. J. Pet. 27, 467–475 (2018). https://doi.org/10.1016/j.ejpe.2017.07.011.
3. Kamali Ardakani, E., Kowsari, E., Ehsani, A.: Imidazolium-derived polymeric ionic liquid as a green inhibitor for corrosion inhibition of mild steel in 1.0 M HCl: Experimental and computational study. Colloids Surf. Physicochem. Eng. Asp. 586, 124195 (2020). https://doi.org/10.1016/j.colsurfa.2019.124195.
4. Rizi, A., Sedik, A., Acidi, A., Rachedi, K.O., Ferkous, H., Berredjem, M., Delimi, A., Abdennouri, A., ALAM, M., Ernst, B., Benguerba, Y.: Sustainable and Green Corrosion Inhibition of Mild Steel: Insights from Electrochemical and Computational Approaches. ACS Omega. 8, 47224–47238 (2023). https://doi.org/10.1021/acsomega.3c06548.
5. Ferkous, H., Sedik, A., Delimi, A., Redjemia, R., Abdesalem, K., Boulechfar, C., Abdennouri, A., Madaci, A., Berredjem, M., Boublia, A., Sajid Ali, M., Jeon, B.-H., Kumar Yadav, K., Benguerba, Y.: A comparative study of novel synthesized sulfamide compounds: Electrochemical, morphological, XPS, and theoretical investigations on copper corrosion inhibition in 1.0 M HCl. J. Mol. Liq. 394, 123781 (2024). https://doi.org/10.1016/j.molliq.2023.123781.
6. Koch, G., Varney, J., Thompson, N., Moghissi, O., Gould, M., Payer, J.: International measures of prevention, application, and economics of corrosion technologies study. NACE Int. 216, 2–3 (2016).
7. Thapa Magar, J., Budhathoki, I.K., Rajaure, A., Oli, H.B., Bhattarai, D.P.: Alkaloid Extract of Ageratina adenophora Stem as Green Inhibitor for Mild Steel Corrosion in One Molar Sulfuric Acid Solution. Electrochem. 4, 84–102 (2023). https://doi.org/10.3390/electrochem4010009.
8. Ferkous, H., Delimi, A., Abdesalem, K., BOULECHFAR, C., Djellali, S., Belakhdar, A., Yadav, K.K., Ali, I., Ahmad, A., Ahn, H.-J., Abdellattif, M., Jeon, B.-H., Benguerba, Y.: Electrochemical and Computational Approaches of Polymer Coating on Carbon Steel X52 in Different Soil Extracts. Polymers. 14, (2022). https://doi.org/10.3390/polym14163288.
9. Lahbib, H., Ben Hassen, S., Gerengi, H., Ben Amor, Y.: Inhibition effect of Cynara cardunculus leaf extract on corrosion of St37 steel immersed in seawater with and without bleach solution. Chem. Eng. Commun. 208, 1260–1278 (2021). https://doi.org/10.1080/00986445.2020.1771320.
10. Ould Sidine, M., Lahbib, H., Hadou, A., Ba, M., Benmessaoud, M., ben amor, Y., Elemine, B.: Usage of Grewia bicolor Juss leaves extract as green corrosion inhibitor for Steel XC40 in sulfuric acid medium. Int. J. Corros. Scale Inhib. 12, 961–983 (2023). https://doi.org/10.17675/2305-6894-2023-12-3-10.
11. Gabsi, M., Ferkous, H., Delimi, A., Boublia, A., Boulechfar, C., Kahlouche, A., Darwish, A.S., Lemaoui, T., Benguerba, Y.: The curious case of polyphenols as green corrosion inhibitors: a review on their extraction, design, and applications. Environ. Sci. Pollut. Res. 30, 59081–59105 (2023). https://doi.org/10.1007/s11356-023-26753-4.
12. Boukerche, S., Ferkous, H., Delimi, A., Sedik, A., Djedouani, A., Otmane Rachedi, K., Bouchoukh, H., Berredjem, M., Zahzouh, M., Himour, A., Bellucci, S., Alam, M., Benguerba, Y.: Anti-corrosion performance of dehydroacetic acid thiosemicarbazone on XC38 carbon steel in an acidic medium. Arab. J. Chem. 16, 105061 (2023). https://doi.org/10.1016/j.arabjc.2023.105061.
13. Madaci, A., Ferkous, H., Sedik, A., Delimi, A., Boulechfar, C., Belakhdar, A., Berredjem, M., Chaouch, M.A., Alam, M., Majdoub, H., Jaffrezic-Renault, N., Benguerba, Y.: Experimental and theoretical study of polysaccharides extracted from prickly pear nopales Pulp (PPUN) of Opuntia ficus-indica as corrosion inhibitors. J. Mol. Liq. 384, 122272 (2023). https://doi.org/10.1016/j.molliq.2023.122272.
14. Belakhdar, A., Ferkous, H., Djellali, S., Sahraoui, R., Lahbib, H., Amor, Y.B., Erto, A., Balsamo, M., Benguerba, Y.: Computational and experimental studies on the efficiency of Rosmarinus officinalis polyphenols as green corrosion inhibitors for XC48 steel in acidic medium. Colloids Surf. Physicochem. Eng. Asp. 606, 125458 (2020).
15. Haldhar, R., Prasad, D., Bhardwaj, N.: Extraction and experimental studies of Citrus aurantifolia as an economical and green corrosion inhibitor for mild steel in acidic media. J. Adhes. Sci. Technol. 33, 1169–1183 (2019). https://doi.org/10.1080/01694243.2019.1585030.
16. Sun, Y., Zhang, Y., Xu, C., Tan, B., Li, W., Zheng, X., Brahmia, A.: Honeysuckle extract as an environment-friendly corrosion inhibitor for copper in sulfuric acid medium. Ind. Crops Prod. 197, 116551 (2023). https://doi.org/10.1016/j.indcrop.2023.116551.
17. Djellali, S., Ferkous, H., Sahraoui, R., Meharga, S.: Efficiency of Alkaloids Crude Extract of Cinnamomum Zeylanicum as Corrosion Inhibitor of Mild Steel in Sulfuric Acid Solution. In: Euro-Mediterranean Conference for Environmental Integration. pp. 1379–1384. Springer (2019).
18. Lahbib, H., Ben Hassen, S., Gerengi, H., Rizvi, M., Ben Amor, Y.: Corrosion inhibition performance of dwarf palm and Cynara cardunculus leaves extract for St37 steel in 15% H2SO4: a comparative study. J. Adhes. Sci. Technol. 35, 691–722 (2021).
19. Belakhdar, A., Ferkous, H., Djellali, S., Sahraoui, R., Lahbib, H., Amor, Y.B.: Corrosion inhibition performance of Rosmarinus officinalis methanolic extract on carbon steel XC48 in acidic medium (2M HCl). Mater. Biomater. Sci. 3, 046–053 (2020).
20. Boulechfar, C., Ferkous, H., Djellali, S., Amin, M.A., Boufas, S., Djedouani, A., Delimi, A., Ben Amor, Y., Kumar Yadav, K., Jeon, B.-H., Benguerba, Y.: DFT/molecular scale, MD simulation and assessment of the eco-friendly anti-corrosion performance of a novel Schiff base on XC38 carbon steel in acidic medium. J. Mol. Liq. 344, 117874 (2021). https://doi.org/10.1016/j.molliq.2021.117874.
Published
2024-06-30
How to Cite
Amdjed, A., Lahbib, H., Delimi, A., Belakhdar, A., & Ferkous, H. (2024). Behavior of Mild Steels by the Action of Corrosion Inhibitors Alone or in Combination in a NaCl Environment. Journal of Engineering Research and Applied Science, 13(1), 2460-2467. Retrieved from http://journaleras.com/index.php/jeras/article/view/345
Issue
Section
Articles
